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Valproic acid was first synthesized in 1882 by Beverly S. Burton as an analogue of valeric acid , found naturally in valerian . [67] Valproic acid is a carboxylic acid , a clear liquid at room temperature. For many decades, its only use was in laboratories as a "metabolically inert" solvent for organic compounds. In 1962, the French researcher Pierre Eymard serendipitously discovered the anticonvulsant properties of valproic acid while using it as a vehicle for a number of other compounds that were being screened for antiseizure activity. He found it prevented pentylenetetrazol -induced convulsions in laboratory rats . [68] It was approved as an antiepileptic drug in 1967 in France and has become the most widely prescribed antiepileptic drug worldwide. [69] Valproic acid has also been used for migraine prophylaxis and bipolar disorder. [70]

Additionally, the WADA list of prohibited substances is not definitive. By necessity the list identifies classes of prohibited substances, such as anabolic agents and related substances and prohibited methods only, rather than publishing a full list of substances. When analyzing a supplement product for contaminants the Prohibited List is unable to act as a checklist for all prohibited substances against which products should be screened — supplement analysis cannot guard against contamination using untried, untested and unknown designer drugs.

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